Very interesting interview. It's nice to see someone with an alternate or semi-fringe hypothesis being able to provide a lucid interview. I always found this topic very fascinating as a big science fiction fan where many authors try to utilize theories of convergence to provide a reasonable explanation for aliens that are still somewhat anthropomorphic in appearance. I've heard authors explain that even on an alien planet things like bilateral symmetry, bipedalism, a brain, spinal cord, etc... are all the inevitable qualities required for a tool making life form. But this does seem to be more of a literary tool than any sort of reality to me.
Not being an evolutionary biologist, I can only offer a very layman's opinion on the subject. It really seems that a lot of what makes us look like we do are really just products of chance that we happened to be evolved from a particular line of ancestors. I don't really see any significant hurdles of an intelligent mollusk involving instead (like depicted in "The Future Is Wild" on the Discovery Channel) or intelligent insect for example. I think it was a gross assumption for the guest to claim that mammals would have out-competed the dinosaurs regardless of the KT-impact. In the presence of gradual climate change, the dinosaurs would have evolved to adapt no differently than other orders of animals. Heck, birds are essentially dinosaurs that evolved into a particular niche. A lot of what makes us successful has purely to do with subtle changes in climate and ecological niches that made our particular type of mammal undergo a selection for intelligence. To me, that is a really chance proposition. Considering an alien ecosystem, even on a completely earth like planet is going to undergo it's own cataclysms and climactic shifts on a completely different schedule would make me think that they could pretty much like like anything. As long as they for whatever reason were being selectively driven to favor more intelligent offspring at some point in their evolutionary history I would think all sorts of bizarre life forms are likely.